Any program sending 2cap ReCaptcha2 requests

[Rarity]

Should any program I run sending 2captcha requests for ReCaptchav2 be intercepted by CapMonster? That was my understanding based on the hosts editing.
I have the module downloaded. Do I just click start and then proceed to running my application?
I can't get CapMonster to generate any solves for my application, and I'm not sure if I'm running it incorrectly.

Does this matter either?
https://imgur.com/a/JiKjS

Thanks in advance for any help with this beginner.

 

[Rarity]

I guess to clarify - I'm running a third-party commercial application that has a 'captcha harvester' that sends requests to 2captcha.com.
What is needed to get the harvester working with CapMonster+Recaptchav2 Module